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comparison between retrosynthetic analysis , chemical synthesis ester alkylation in 1967, e. j. corey introduced concept of synthon in retrosynthetic analysis. planning steps of complex molecule synthesis requires recognizing key synthons , identifying how can assembled desired product. in many retrosynthetic bond disconnections, bond broken heterolytically instead of homolytically, generating carbocationtic , carbanionic synthon. polar-mechanism reactions, whether nucleophilic displacements, 1,2-carbonyl additions, michael reactions, or other processes, involve fusion of nucleophilic fragment , electrophilic fragment. there wide variety of carbanionic synthons available organic chemist construction of complex molecules. these include enolates, organometallics, acetylides, malonates, , carbanions generated in situ after addition olefins. example of carbanionic synthon ester enolate shown in fig. 1. carbon-carbon bond alpha carbonyl can disconnected enolate equivalent , carbon electroph...

1 district 17 1.1 endorsements 1.2 polling 1.3 results district 17 democratic incumbent chet edwards challenged republican nominee bill flores , libertarian nominee richard b. kelly (pvs). in 2008, edwards reelected 53% republican small business owner rob curnock, overwhelmingly outspent. edwards moderate democrat, represents 1 of conservative districts in nation. in 2010, went uncontested in democratic primary. in republican primary, curnock qualified run off election against flores. flores won run off 64% of vote. campaign contributions center responsive politics race profile @ new york times endorsements the dallas morning news , fort worth star-telegram have both endorsed edwards. polling results

the history of eastwoodhill arboretum remain permanently connected life of william douglas cook (1884–1967). douglas cook, cookie close friends, born 28 october 1884 @ new plymouth, new zealand. in 1910, established farm of 250 hectares in ngatapa settlement, calling property eastwoodhill , after mother s family home in thornliebank near glasgow. first foundations present arboretum laid then. douglas cook started creating garden immediately. planted trees, roses, flowers, shrubs , vegetables. during first world war, cook volunteered serve in army. in france, lost sight of right eye , subsequently stayed in scotland family recover. inspired gardens , parks of england , came in contact sir arthur william hill, later become director of kew gardens. in 1918, @ eastwoodhill, douglas cook started planting thousands of pinus radiata wood production , fire-wood. planted eucalyptus viminalis , e. macarthurii. started creating parkland with, amongst others, platanus orientalis, different kinds ...

1 history 1.1 virgin mobile india 1.1.1 marketing 1.2 rebranding 1.3 ntt docomo exit history tata docomo part of indian conglomerate tata group. company received license operate gsm services in nineteen telecom circles , allotted spectrum in eighteen of these circles , launched gsm services on 24 june 2009. began operations first in south india , operates gsm services in eighteen of twenty 2 telecom circles. has licences operate in delhi has not been allocated spectrum government. docomo provides services throughout india. tata docomo offers both prepaid , postpaid cellular phone services. has become popular one-second pulse in semi-urban , rural areas. on 12 october 2017 tata docomo acquired bharti airtel , subject regulatory obligations. in november 2008, ntt docomo invested ₹12,740 crore (equivalent ₹220 billion or us$3.5 billion in 2016) in tata teleservices, @ ₹117 (equivalent ₹210 or us$3.20 in 2016) share 26.5% stake in latter. docomo, ttsl , tata sons had in march 2009...

1 career 1.1 career 1.2 eastenders 1.3 other work career early career westbrook started off modelling @ age of 7 supermarket asda. went on launch next s children s fashionware, became face of highstreet store tammy girl , took part in weetabix campaign , featured in advertisements opel cars , coca-cola. later did modelling alongside younger brother jay. progressed acting, appearing child thief in melvyn bragg s london programme , west end production of joseph , amazing technicolor dreamcoat. appeared in video song invisible man queen , had minor role in grange hill. @ age of eleven appeared in bbc soap opera eastenders, roller skating across soap s setting of albert square. @ time local paper published picture punchline knows, 1 day may show s star! . eastenders at age of 16, westbrook put forward bigger role in eastenders, sam mitchell (the younger sister of phil , grant). audition successful , first appearance on eastenders aired in july 1990. despite featuring in prominent storyli...

amtrak train on empire builder route departs chicago union station amtrak long distance , commuter rail services originate union station. chicago 1 of largest hubs of passenger rail service in nation. services terminate in san francisco, washington, d.c., new york city, indianapolis, new orleans, portland, seattle, milwaukee, quincy, st. louis, carbondale, boston, grand rapids, port huron, pontiac, los angeles, , san antonio. attempt made in 20th century link chicago new york city via chicago – new york electric air line railroad. parts of built, never completed.

^ christus koning (vredeskerk) . kerkgebouwen in limburg. retrieved 29 april 2017.  ^ cite error: named reference schrijvers invoked never defined (see page). ^ hall of memories . new zealand ministry culture , heritage. 15 jan 2015. retrieved 25 jan 2015.  ^ st. mary, banbury, oxon . oxford diocesan guild of church bell ringers. 2009. retrieved 25 jan 2015. 

longacre s initials jbl on cutoff of bust on obverse representations of america female native american, or indian princess, dated 16th century; cartographers place native woman, wearing feathered headdress, upon version of north american continent. evolved image of indian queen, indian princess, , although columbia came favored female embodiment of united states, image of indian princess survives in popular view of such figures pocahontas , sacagawea. some sources suggest longacre may have based features of liberty on of daughter, sarah. story more associated longacre s indian head cent, features of liberty on both coins (and type gold dollar, double eagle, , three-cent nickel piece) identical. distinguish new coin quarter eagle or $2.50 piece, longacre used thinner planchet, or blank, make piece greater in diameter. flattened planchet of gold dollar enlarge it, , gave same indian princess design. reverse originates longacre s agricultural wreath of corn, tobacco, cotton, , ...

1 attractions 1.1 villa fridheim 1.2 krøderbanen 1.3 norefjell ski resort attractions villa fridheim villa fridheim, manor house houses folk museum, 1 of norway s largest timber buildings. style representative of romantic nationalism. building erected in 1890-92 country house of drammen based timber merchant svend haug(1832-1891) , wife anne marthea (thea) sveaas (1839-1924). architect herman major backer (1856-1932), other commissions included skaugum in asker, klemetsrud church in oslo, sollihøgda chapel in hole , st john s church in bergen. the building functioned hotel , boarding house between 1914-60. building restored , opened folktale museum in summer of 1986. in 1996 museum opened section dedicated great collectors of norwegian fairy tales, peter christen asbjørnsen , jørgen moe , noted illustrators theodor kittelsen , christian skredsvig. krøderbanen krøderbanen museum (museet krøderbanen) railroad museum headquartered in former krøderen railroad station @ krøderen. krøderbane...

1984: apple macintosh. in 1983 apple computer introduced first mass-marketed microcomputer graphical user interface, lisa. lisa ran on motorola 68000 microprocessor , came equipped 1 megabyte of ram, 12-inch (300 mm) black-and-white monitor, dual 5¼-inch floppy disk drives , 5 megabyte profile hard drive. lisa s slow operating speed , high price (us$10,000), however, led commercial failure. drawing upon experience lisa, apple launched macintosh in 1984, advertisement during super bowl. macintosh first successful mass-market mouse-driven computer graphical user interface or wimp (windows, icons, menus, , pointers). based on motorola 68000 microprocessor, macintosh included many of lisa s features @ price of us$2,495. macintosh introduced 128 kb of ram , later year 512 kb ram model became available. reduce costs compared lisa, year-younger macintosh had simplified motherboard design, no internal hard drive, , single 3.5 floppy drive. applications came macintosh included macpaint, ...

figure iii: direct hot pressing the basic idea of sintering electric current going through mold quite old. resistance heating of cemented carbide powders patented tayler 1933. method undergoing renewed interest. when applying standard (unpulsed) ac or dc current, referred fast direct hot pressing (fast dhp) , common term in many industries. common term rapid hot pressing (rhp) . when applying pulsed dc current, referred spark plasma sintering (sps) . both techniques summarized under generic term field assisted sintering technique (fast) . the compelling reason shortening cycle time avoid grain growth , save energy. in direct hot pressing, mold directly connected electrical power. resistivity of mold , powder part generates heat directly in mold. results in high heating rates. additionally, leads significant increase in sintering activity of fine metal powder aggregates makes short cycle times of few minutes possible. further, process lowers threshold sintering temperature , pressur...

image surgical casebook (kishitsu geryō zukan) hanaoka seishu agar agar discovered in japan around 1658 mino tarōzaemon. aspergillus oryzae the genome aspergillus oryzae sequenced , released consortium of japanese biotechnology companies, in late 2005. crispr yoshizumi ishino discovered crispr in 1987. ephedrine synthesis ephedrine in natural form, known má huáng (麻黄) in traditional chinese medicine, had been documented in china since han dynasty. however, not until 1885 chemical synthesis of ephedrine first accomplished japanese organic chemist nagai nagayoshi. epinephrine (adrenaline) japanese chemist jokichi takamine , assistant keizo uenaka first discovered epinephrine in 1900. in 1901 takamine isolated , purified hormone adrenal glands of sheep , oxen. esophagogastroduodenoscope mutsuo sugiura japanese engineer famous being first develop gastro-camera (a present-day esophagogastroduodenoscope). story illustrated in nhk tv documentary feature, project x: challengers: development...

tourist information centre in 19th century farming became less economic when construction of reservoirs reduced amount of agricultural land in village. weaving industry mechanised, small mines closed , population declined further when properties in village demolished in 20th century. agriculture, sheep farming, continues although on small scale. tourism @ rivington began in victorian times , after reservoirs filled in 1860s known little lake district. rivington became popular destination when lever park opened in 1904. late victorian period until mid-20th century tourists bolton travelled on day trips tram along chorley new road , on rivington on foot, many more visitors arrived train. today thousands of visitors attracted village, rivington pike , lever park every year, making tourism significant source of income in area. go ape operates outdoor activity centre in country park.

these elected officials of municipality of barugo result of 2016 elections: mayor: avestruz, ma. rosario c. vice mayor: tiu, josephine c. members of sangguniang bayan: badiable, rodolfo cabanacan, jesus b. avestruz, efren a. canezal, jeffrey apostol, oscar l. arpon, antonio c. astorga, marilyn a. ayes, frederico jr. a.

south carolina signee jadeveon clowney attempts sack tennessee signee justin worley on august 28, 2010 south pointe has seen great success on gridiron in limited time school has been around. struggled in first 2 varsity years in 2006 , 2007. broke out undefeated 15-0 record in 2008, winning division ii aaaa state championship. lost in aaaa upper state championship in 2009 , suffered defeat in 2010 aaa state championship. won second state championship in 2011 aaa state championship going 14-1 year. stallions made 2012 aaaa upper state championship before being defeated greenwood high school 35-31. south pointe s varsity , junior varsity coached head coach strait herron. south pointe s ninth grade team coach head coach lance roberts.

in december 2016, first amazon go store opened amazon employees in seattle. 1,800 sq ft store uses variety of sensors , automatically charges shopper s amazon account when walk out of store. stocks ready-made meals , meal boxes; in addition full grocery store. store planned open general public in 2017 has not done due issues technology tracking on twenty people @ 1 time. the amazon go store.

1 formula renault 2.0l 1.1 formula renault 2.0 eurocup series 1.2 formula renault 2.0 west european cup season 1.3 formula renault 2.0 uk season 1.3.1 formula renault 2.0 uk winter cup 1.4 formula renault barc fr2000 series 1.4.1 formula renault barc club class series 1.4.2 formula renault barc winter cup 1.5 formula renault 2.0 italia season 1.5.1 formula renault 2.0 italia winter series 1.6 formula renault 2.0 northern european cup season 1.7 lo formule renault 2.0 suisse season 1.8 fórmula júnior fr2.0 portugal season 1.8.1 fórmula júnior fr2.0 portugal(portugal winter series fr2.0) 1.9 formule renault 2.0 finland season 1.10 formula renault 2000 de america season 1.11 fórmula renault 2.0 brasil season 1.12 asian formula renault challenge season formula renault 2.0l formula renault 2.0 eurocup series see 2008 eurocup formula renault 2.0 season formula renault 2.0 west european cup season the formula renault 2.0 west european cup first season wec series. includes french formula renau...

adult @ são paulo zoo, brazil various initiatives restoration of species in place in various countries. since 2002, peregrine fund initiated conservation , research program harpy eagle in darién province. similar—and grander, given dimensions of countries involved—research project occurring in brazil, @ national institute of amazonian research, through 45 known nesting locations (updated 62, 3 outside amazonian basin , 3 inactive) being monitored researchers , volunteers local communities. harpy eagle chick has been fitted radio transmitter allows tracked more 3 years via satellite signal sent brazilian national institute space research. also, photographic recording of nest site in carajás national forest made brazilian edition of national geographic magazine. adult in belize in belize, belize harpy eagle restoration project began in 2003 collaboration of sharon matola, founder , director of belize zoo , peregrine fund. goal of project re-establishment of harpy eagle within belize. pop...

1 hardware support 1.1 hardware requirements 1.2 architecture ports 1.2.1 official ports 1.2.2 unofficial ports 1.3 embedded systems hardware support hardware requirements hardware requirements @ least of kernel , gnu toolsets. debian s recommended system requirements depend on level of installation, corresponds increased numbers of installed components: the real minimum memory requirements depend on architecture , may less numbers listed in table. possible install debian 60 mb of ram x86-64; installer run in low memory mode , recommended create swap partition. installer z/architecture requires 20 mb of ram, relies on network hardware. similarly, disk space requirements, depend on packages installed, can reduced manually selecting packages needed. of august 2014, no pure blend exists lower hardware requirements easily. it possible run graphical user interfaces on older or low-end systems, installation of window managers instead of desktop environments recommended, desktop envi...

1 career 1.1 2003–2012: beginnings 1.2 2013–2015: bet s 106 , park 1.3 2016–present: new music career 2003–2012: beginnings in 2002, @ age of 14, sonymusic canada signed chante long term record contract release music in canada. in 2003, released shook (the answer) won urban music award best pop/r&b single . follow-up, unpredictable went #3 on radio charts, , first video hit number 1 on ytv , top ten on muchmusic. in november 2003, cd single of unpredictable certified gold , later went on win chante canadian radio music award best new solo artist . in february 2004, chanté s third single, bad boy , released. successful, breaking top 10 on radio , sitting @ #3 on muchmusic 4 weeks before later earning #1 position on chart. video directed director x. later, in june 2004, chanté s fourth single love me? ft. foxy brown reached top 5 @ radio. video directed director x , became #1 on muchmusic 3 weeks. video garnered urban music video award video of year . on june 22, 2004 cha...

1 helon in bible 1.1 genesis / bereishith / בְּרֵאשִׁית ~ in beginning 1.1.1 genesis 36:2 - adah: wife of esau 1.1.2 genesis 46:14 - helon: son of zebulon (see numbers 26:26) 1.2 numbers / bamidbar / במדבר ~ in wilderness 1.2.1 numbers 26:26 - helon: son of zebulon , progenitor of helonite clan (see genesis 46:14) 1.2.2 numbers 1:9 - helon: first census in sinai wilderness 1.2.3 numbers 2:7 - helon: camp arrangement of tribes of israel 1.2.4 numbers 7:24 & 29 - helon: offerings of tribes of israel 1.2.5 numbers 10:16 - helon: israelites prepare break camp 1.3 judges / shoftim / שׁוֹפְטִים ~ judges 1.3.1 judges 12:11–12 - helon judge of israel (circa 1083–1073 b.c.) 1.4 noncanonical biblical texts helon in bible helon ben akhar ben (a direct descendant of) zebulon judged israel 10 years (circa 1083–1073 b.c.). fragment historical chronology of deeds of patriarchs, leaders, judges, kings, , priests of hebrew people: rome; 1751; p. 318. the first century romano-jewish historian joseph...

1 categorization 1.1 connected pacs 1.2 non-connected pacs 1.2.1 leadership pacs 1.2.2 controversial use of leadership pacs 1.3 super pacs 1.3.1 2012 presidential election 1.3.2 2016 presidential election 1.3.3 disclosure rules categorization federal law formally allows 2 types of pacs: connected , non-connected. judicial decisions added third classification, independent-expenditure committees, colloquially known super pacs . connected pacs most of 4,600 active, registered pacs connected pacs established businesses, labor unions, trade groups, or health organizations. these pacs receive , raise money restricted class , consisting of managers , shareholders in case of corporation , members in case of union or other interest group. of january 2009, there 1,598 registered corporate pacs, 272 related labor unions , 995 trade organizations. non-connected pacs groups ideological mission, single-issue groups, , members of congress , other political leaders may form non-connected pacs . t...

publication history red guardian first appeared in captain america #352-353 (april–may 1989), , created mark gruenwald , kieron dwyer. the character subsequently appears in avengers #319-324 (july–october 1990), incredible hulk #393 (may 1992), , soviet super-soldiers #1 (november 1992). character subsequently appears steel guardian in iron man #9 (october 1998). red guardian appeared part of supreme soviets entry in official handbook of marvel universe update 89 #7. fictional character biography the fourth red guardian, josef petkus, special operative intelligence agencies of soviet union, , appeared member of militant supreme soviets. alongside supreme soviets, attacked soviet super-soldiers defecting soviet union. alongside captain america, later battled bear-like creature composed of darkforce. supreme soviets later became known people s protectorate. alongside people s protectorate, teamed avengers , alpha flight battle peace corpse, atlantean army, , combine. petkus later join...

1 trivial cases 1.1 sphere lies entirely within cylinder 1.2 sphere touches cylinder in 1 point 1.3 sphere centered on cylinder axis trivial cases sphere lies entirely within cylinder if a + r < r {\displaystyle a+r<r} , sphere lies entirely in interior of cylinder. intersection empty set. sphere touches cylinder in 1 point if sphere smaller cylinder ( r < r {\displaystyle r<r} ) , a + r = r {\displaystyle a+r=r} , sphere lies in interior of cylinder except 1 point. intersection single point ( r , 0 , 0 ) {\displaystyle (r,0,0)} . sphere centered on cylinder axis if center of sphere lies on axis of cylinder, a = 0 {\displaystyle a=0} . in case, intersectio...

grave , bust ludwig manzel in stahnsdorf southwestern cemetery. murnau s memorial plaque in berlin. a week prior opening of film tabu, murnau drove pacific coast highway los angeles, california in hired rolls-royce. young driver, 14-year-old filipino servant, crashed car against electric pole. murnau hit head , died in hospital next day, in nearby santa barbara, before premiere of last film. murnau entombed in southwest cemetery in stahnsdorf (südwest-kirchhof stahnsdorf) near berlin. 11 people attended funeral. among them robert j. flaherty, emil jannings, greta garbo , fritz lang, delivered eulogy. garbo commissioned death mask of murnau, kept on desk during years in hollywood. in july 2015 murnau s grave broken into, remains disturbed , skull removed persons unknown. wax residue reportedly found @ site, leading speculate candles had been lit, perhaps occult or ceremonial significance. disturbance not isolated incident, cemetery managers considering sealing grave.

– jeremy mckinnon, on album art, 2009 a live video of band performing mr. highway s thinking end included in episode of victory s victorv.for subsequent tours in promotion of homesick, band had line-up change adding 4 letter lie guitarist kevin skaff , dropping tom denney, latter of whom wanted settle down, still working band behind scenes. video of band performing m made of wax, larry, made of? , filmed on warped tour, added band s myspace profile on october 16, 2009. included dvd trailer on profile, people mistook song s actual music video. in december, band released christmas song, right want me , on myspace account. music videos , live performances also in december, music video m made of wax, larry, made of? filmed, directed dan dobi. in march 2010 band announced via twitter account video set release, date of march 16. further confirmed few days later, fans being able view before release. delay in releasing occurred band trying negotiate mtv, westfall commented: think s more...

laotians hired assist u.s. troops assigned joint pow/mia accounting command sift move tons of dirt on mountain near xépôn, laos (july 2004) unexploded cluster sub-munition, blu-26 type. plain of jars, laos. 2012 due vietnam war, laotian war had been forgotten majority of people in around world, in united states , vietnam. twenty-two years following end of laotian war, on 15 may 1997, u.s. officially acknowledged role in secret war. memorial honor of american , hmong contributions u.s. air , ground combat efforts during conflict established lao veterans of america, center public policy analysis, in cooperation congress , others. laos memorial located on grounds of arlington national cemetery between john f. kennedy eternal flame , tomb of unknown soldier. many former ethnic hmong , laotian veterans , families, led colonel wangyee vang of lao veterans of america institute , lao veterans of america worked establish non-profit organization , advocate honorary u.s. citizenship secret army v...

1 manufacturing process 1.1 cleaning 1.2 cooking grains 1.3 dicing vegetables 1.4 combining grains , vegetables 1.5 mirepoix 1.6 addition of dry ingredients 1.7 forming patties 1.8 baking patties 1.9 quick freezing 1.10 vacuum packaging 1.11 overview video manufacturing process cleaning the grains , vegetables used in patties first washed , thoroughly cleaned ensure removal of dirt, bacteria, chemical residues, , other materials may on raw products. process can either done hand or through use of machinery such high-pressure sprayers. use of conveyor belt, food moved along under high pressure sprayer remove debris listed above. method may used companies use of hollow drum circulates food while water sprayed onto remove debris. cooking grains grains of rice before cooking next, steam-heated mixer used cook grain , remove debris , excess water. mixer typically has oils within (such safflower oil). oil simmers, grains gradually added in , blades used mix grains around. steam created in mix...

1 reforms 1.1 anti-slavery 1.2 anti capital punishment 1.3 status of women reforms anti-slavery in 1766, when rush set out studies in edinburgh, outraged sight of 100 slave ships in liverpool harbor. prominent presbyterian doctor , professor of chemistry in philadelphia, provided bold , respected voice against slave trade. he warmly praised ministry of black harry hosier, freedman circuit rider accompanied bishop john asbury during establishment of methodist church in america, highlight of involvement pamphlet wrote in 1773 entitled address inhabitants of british settlements in america, upon slave-keeping. in first of many attacks on social evils of day, assailed slave trade entire institution of slavery. rush argued scientifically negroes not nature intellectually or morally inferior. apparent evidence contrary perverted expression of slavery, foreign human mind, moral faculties, of understanding debased, , rendered torpid it. in 1792, rush read paper before american philosophica...

many of school s activities students , staff outside normal operating hours, including debating, sports, , science. coláiste rís regarded 1 of strongest schools in country irish debating, school debate team has reached all-ireland irish debating championship last eleven years in row. seán Ó coigligh, irish teacher in coláiste rís, has played key role in preparing teams every year. the school has long had accomplished record in sporting field, in gaelic football , in hurling, soccer. in science, colaiste rís second none in county louth having track record of winners @ annual young scientist competition. students have collected countless awards competition, including awards irish geological society, irish association of speech therapists, , many others. outstanding student in regard thomas gernon, won prizes in years 1997, 1998, 1999 , 2000. in 2000 overall winner of competition, , became irish young scientist of year. thomas went amsterdam , collected prize in pan-european competition. ...

1 four-digit major command-controlled squadrons 1.1 communications squadrons 1.2 airways , air communications service squadrons 1.3 usaf communications squadrons four-digit major command-controlled squadrons communications squadrons airways , air communications service squadrons the first airways , air communications service (aacs) squadrons formed on 1 june 1948, when united states air force (usaf) discontinued army air forces base unit system while implementing wing base reorganization (hobson plan). on 1 october 1948, active aacs squadrons renumbered starting @ 1900 when usaf required major command controlled units have 4 digits contained within blocks of numbers allotted commands. aacs squadrons active on 1 june 1961 redesignated communications squadrons. squadrons numbered in 1200s renumbered in 2100s retaining last 2 digits of aacs number. usaf communications squadrons [1] emblems

cumans depicted in radziwiłł chronicle after byzantine victory, courtier stated theodor-peter , asen forced yield emperor, describing theodor-peter bull had broken yoke. however, brothers fled across lower danube , sought assistance cumans. imperial troops set fire crops gathered in heaps local inhabitants, made no major efforts capture rebels fortresses built on sheer cliffs , cloud-capped peaks . isaac ii failed garrison castles along lower danube, enabling refuges return, accompanied cuman troops in autumn of 1186. theodor-peter had promised rich booty , salary cumans talk them supporting him, according letter niketas choniates wrote on emperor s name year after events. same author attributed leading role asen in ensuing military campaign in chronicle. rebels , cuman allies invaded byzantine empire , took control of paristrion (or moesia) between lower danube , mountains. thereafter unification of moesia , bulgaria 1 empire of old (namely, restoration of first bulgarian empire...